Fig 13.14 IPCC. 2013.
Grant et al. 2014.
source: NASA JPL
source: www.youtube.com/watch?v=olFzcye4iSs
$\Theta = \frac{h^0}{c_p^0}$
where $c_p^0 =$ 3991.867 957 119 63 J kg$^{-1}$ K$^{-1}$
For seawater with a standard composition:
$S_A = S_R = \left( \frac{35.165 04 g kg^{-1}}{35} \right) S_P$, g kg$^{-1}$
Otherwise:
$S_A = S_R + \delta S_A$
where the Absolute Salinity anomaly, $\delta S_A$, requires spatial interpolation of global dataset.
Modified EOS for boussinesq models following Roquet et al. 2015. Ocean Modelling
Huppert & Turner, Nature. 1978.
$Q^T = -\rho c_p k^T \nabla T + \frac{B \mu_{S_A}}{\rho k_S T} Q^S$
Assuming the cross-diffusion coefficient $B$ can be taken to be zero, the molecular diffusion of heat is proportional to the gradient of in situ temperature, or Fourier's Law
$Q_w^S = -\rho k^S \left( \nabla S_A + \frac{\mu_{,P}}{\mu_{,{S_A}}} \nabla P \right) - \left[\frac{\rho k^S T}{\mu_{,{S_A}}} \left( \frac{\mu}{T} \right)_{,T} + \frac{B}{T^2} \right] \nabla T$
which shows, in the absence of a temperature gradient $\nabla T = 0$, the salt flux is proportional to both the salinity gradient and $\rho \kappa_S \frac{\mu_{,P}}{\mu_{,{S_A}}} \nabla P$, known as ``barodiffusion'' as it causes a flux of salt down the gradient of pressure.
Assuming the film is thin enough that the processes are occurring at constant pressure, $\frac{\mu_{,P}}{\mu_{,{S_A}}} \nabla P = 0$, and the cross-diffusion terms $B = 0$, then the conventional form of the salt flux equation, Fick's Law, is:
$Q_w^S = -\rho k^S \nabla S_A $
However, for a temperature gradient not equal to zero, then the expression for the salt flux is:
$Q_w^S = -\rho k^S \nabla S_A - \left[ \frac{\rho k^S T}{\mu_{,{S_A}}} \left( \frac{\mu}{T} \right)_{,T} \right] \nabla T$
The second term on the R.H.S. is a flux of salt due to the gradient of in situ temperature and is called the Soret effect.
For polar oceans under ice, diffusion driven by the Soret effect is about $S_T$ times the diffusion driven by the gradient in salinity alone, also known as Fick’s Law.
The Soret effect becomes more important with decreasing salinity gradients.
Gwyther et al. 2016.
$Q_{latent} = Q_M - Q_I$
$Q_M \gg Q_I$
$\rho_i L m = \rho c_w \gamma_T (T_M-T_B)$
$\rho_i L m = \rho c_w \gamma_T (T_M-T_B)$
$\rho_i S_B m = \rho \gamma_S (S_M-S_B)$
$T_B = T_{linear freezing}(S_B,P)$
$\gamma_t = \frac{\kappa_t Nu}{h} = f(u^{\star}, Pr)$
$\gamma_S = \frac{\kappa_S Sh}{h} = f(u^{\star}, Sc)$
Functions are parameterized from boundary layer observations under sea-ice, e.g. McPhee, 2008.
Not consistent with ROMS turbulence closure model.
Large Eddy Simulation. Gayen et al. 2015
Is there need for different values of $\gamma$ for S and T?
source: ROV, MBARI, Weddell Sea
Assuming the total transfer, is the sum of the molecular, $\kappa$, and turbulence, $K$, diffusivities
$Nu = (\kappa_t + K)/\kappa_t$
$Sh = (\kappa_S + K)/\kappa_S$
then
$\gamma_t = \frac{\kappa_t + K}{h}$
$\gamma_S = \frac{\kappa_S + K}{h}$
where, $K$ is the component of the exchange velocity due to turbulence alone, and can be provided by a turbulence closure model.
$K \gg \kappa_t$ and $K \gg \kappa_S$ and thus
$\gamma_t \approx \gamma_S$.
A useful value of $h$ is the model uppermost layer thickness, $\Delta z$, where the values of $T$, $S$ and $K$ are found.
Galton-Fenzi, unpublished
Galton-Fenzi, unpublished